Takahiro Sato

Polyisocyanates, long studied as theoretical models for wormlike chains in dilute solution and liquid crystals, differ from their biological helical analogs in the absence of a pre-determined helical sense. These polymers have an unusual sensitivity to chiral effects that arises from a structure in which alternating right- and left-handed long helical blocks are separated by infrequent and mobile helical reversals. Statistical thermodynamic methods yield an exact description of the polymer and the cooperative nature of its chiral properties. Minute energies that favor one of the helical senses drive easily measurable conformational changes, even though such energies may be extremely difficult to calculate from structural theory. In addition, the chiral nature of the polymer can be used to test theoretical ideas concerned with cholesteric liquid crystals, one of which solves the problem of assigning the helical sense.

Cooperative phenomena, described by one-dimensional statistical physical methods, are observed between the enantiomeric characteristics of monomeric materials and the polymers they produce. The effect of minute energies associated with this amplified chirality, although currently not interpretable, can be easily measured. Nonlinear relationships between enantiomeric excess or enantiomeric content and polymer properties may offer the possibility of developing chiral catalysts and chiral chromatographic materials in which the burden of large enantiomeric excess or content may be considerably alleviated. New approaches to information and sensor technology may become possible.

Experiment E949 at Brookhaven National Laboratory has observed three new events consistent with the decay ${K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}\ensuremath{\nu}\overline{\ensuremath{\nu}}$ in the pion momentum region $140<{P}_{\ensuremath{\pi}}<199\text{ }\text{ }\mathrm{MeV}/c$ in an exposure of $1.71\ifmmode\times\else\texttimes\fi{}{10}^{12}$ stopped kaons with an estimated total background of $0.93\ifmmode\pm\else\textpm\fi{}0.17(\mathrm{stat}{)}_{\ensuremath{-}0.24}^{+0.32}(\mathrm{syst})$ events. This brings the total number of observed ${K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}\ensuremath{\nu}\overline{\ensuremath{\nu}}$ events to seven. Combining this observation with previous results, assuming the pion spectrum predicted by the standard model, results in a branching ratio of $\mathcal{B}({K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}\ensuremath{\nu}\overline{\ensuremath{\nu}})=({1.73}_{\ensuremath{-}1.05}^{+1.15})\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}$. An interpretation of the results for alternative models of the decay ${K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}+nothing$ is also presented.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDouble-stranded helix of xanthan: dimensional and hydrodynamic properties in 0.1 M aqueous sodium chlorideTakahiro Sato, Takashi Norisuye, and Hiroshi FujitaCite this: Macromolecules 1984, 17, 12, 2696–2700Publication Date (Print):December 1, 1984Publication History Published online1 May 2002Published inissue 1 December 1984https://pubs.acs.org/doi/10.1021/ma00142a043https://doi.org/10.1021/ma00142a043research-articleACS PublicationsRequest reuse permissionsArticle Views706Altmetric-Citations211LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

Three events for the decay ${K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}\ensuremath{\nu}\overline{\ensuremath{\nu}}$ have been observed in the pion momentum region below the ${K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}{\ensuremath{\pi}}^{0}$ peak, $140<{P}_{\ensuremath{\pi}}<199\text{ }\text{ }\mathrm{MeV}/c$, with an estimated background of $0.93\ifmmode\pm\else\textpm\fi{}0.17(\mathrm{stat}.{)}_{\ensuremath{-}0.24}^{+0.32}(\mathrm{syst}.)$ events. Combining this observation with previously reported results yields a branching ratio of $\mathcal{B}({K}^{+}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}\ensuremath{\nu}\overline{\ensuremath{\nu}})=({1.73}_{\ensuremath{-}1.05}^{+1.15})\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}$ consistent with the standard model prediction.